JP Food Sanitation Law "Positive List" for Pesticide Residue

FUJIFILM Wako offers over 1100 standard products ((certified reference material (CRM), single standards and standard mixture solutions)) for the "positive list" in Japan. Our CRM and standard products are highly purified based on our purification technology. The purity of almost all products is determined by qNMR. The high-quality standard products are essential for making chromatographic measurements and their assured values are important for final analytical results. qNMR using reference standards with traceability to the International System of Units (SI) recently attracts attention as one of absolute purity determining methods for standards for chromatography, because of its efficiency and reliability. In fact, qNMR has been used as the official analytical method regarding the Japanese Pharmacopoeia, Japanese Standards for Food Additives, and the Japanese Industrial Standard. We started to establish a supply system for standard products with absolute purity values determined by qNMR. We explored an appropriate framework for sample preparation procedures, NMR parameter sets, sample distribution ways and selection of target signal(s) of each compound. As a result, we found that qNMR was able to determine the purity of normal small molecular organic compounds with the accuracy of less than or equal to 1%. We established a supply system for standard products of very high purity such as pesticides, catechins, amino acids, natural toxins (e.g. mycotoxin), dietary supplements, and functional compounds.

Catalog

PPL1-PPL5
PPL6-PPL10
PPL11-PPL15
PPL16-PPL17
VPL1-VPL2
Product List
Related Information

PPL1-PPL5

Pesticide Mixture Standard Solution PL-1-2 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	Omethoate	156	110	141	11	Malathion (Malathon)	173	158		21	Pyrethrin I, II	123	133	162
1	Omethoate	156	110	141	11	Malathion (Malathon)	173	158		21	Pyrethrin I, II	107	133	160
2	Trifluralin	306	264		12	Fenpropimorph	128	129	303	22	Norflurazon	145	303	173
3	Dimethoate	87	125		13	Pendimethalin	252	281		23	Diflufenican	266	394
4	Atrazine	200	215		14	Penconazole	159	248		24	Bifenthrin	181	166
5	Terbufos	231	288	153	15	Procymidone	283	285		25	Azinphos-methyl	160	132
6	Tefluthrin	177	197	383	16	Methidathion (DMTP)	145	85	302	26	Fenarimol	139	330	251
7	Spiroxamine	100	126		17	Fenamiphos	303	217		27	trans-Permethirn	183	163
7	Spiroxamine	100	101	126	17	Fenamiphos	303	217		27	trans-Permethirn	183	163
8	Chlorpyrifosmethyl	286	288		18	Oxadiazon	175	302	344	28	cis-Permethirn	183	163
9	Terbutryn	226	241		19	Kresoxim-methyl	116	206		29	Cyfluthrin	163	226	206
10	Thiobencarb (Benthiocarb)	100	257		20	Chlorfenapyr	364	328		30	Flucythrinate	199	451
										31	Fluvalinate	250	252

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010 Ultra

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-2-1 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Peak No.	Constituent	Monitoring Ions (m/z)		Peak No.	Constituent	Monitoring Ions (m/z)
1	Propoxur (PHC)	110	152	11	Isofenphos Oxon	229	314	21	Propiconazole	173	259
2	Carbofuran	164	149	12	Chlorfenvinphos(α-CVP, β-CVP)	267	323	22	Hexazinone	171	252	128
3	Quintozene (PCNB)	237	295	13	Isofenphos	213	255	23	Propargite (BPPS)	173	150
4	Propyzamide	173	255	14	Triadimenol	112	168	24	Phosmet (PMP)	160	161	133
5	Tri-allate	268	128	15	Tetrachlorvinphos (CVMP)	329	331	25	Methoxychlor	227	274	228
6	Vinclozolin	285	212	16	Isoprothiolane	118	290	26	Pyriproxyfen	136	226
7	Alachlor	160	188	17	Myclobutanil	179	150	27	Pyraclofos	360	194
8	Fenitrothion (MEP)	277	260	18	Buprofezin	105	172	28	Fluquinconazole	340	108
9	Metolachlor	162	238	19	Cyproconazole	222	139	29	Fenbuconazole	129	198
10	Fenthion (MPP)	278	169	20	Ethion	231	384	30	Fluridone	328	329
								31	Difenoconazole	323	265

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010 Ultra

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-3-3 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	Ethoprophos	158	200	139	11	Fipronil	367	369	351	21	Fenpropathrin	181	265	349
2	Simazine (CAT)	201	173		12	Flutolanil	173	323		22	Cyhalothrin	181	197	208
3	Diazinon	137	152	304	13	Profenofos	139	337	374	23	Bitertanol	170	168	112
4	Propanil (DCPA)	161	217		14	Oxyfluorfen	252	361	300	24	Pyridaben	147	309
5	Parathion-methyl (Methylparathion)	125	233	263	15	Chlorobenzilate	139	251		25	Cypermethrin	163	181	165
6	Pirimiphos-methyl	290	276	305	16	Triazophos	161	257		26	Fenvalerate	125	419	225
7	Chlorpyrifos	197	286	314	17	Quinoxyfen	237	272	307	27	Deltamethrin	181	253
8	Parathion	291	235		18	Tebuconazole	125	250
9	Triadimefon	208	181		19	Acetamiprid	166	221
10	Allethrin	123	136		20	Bromopropylate (Phenisobromolate)	341	183

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010 Ultra

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-4-2 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	Mevinphos ( (E)-Mevinphos, (Z)-Mevinphos)	127	109	192	13	Chlorthal-dimethyl (TCTP)	301	299	332	25	Fluacrypyrim	145	320	189
2	Tecnazene	203	215	261	14	Fthalide	243	241	272	26	Lenacil	153	154	110
3	Ethalfluralin	276	316		15	Fosthiazate	139	166	283	27	(E)-Pyriminobac-methyl	302	256	303
4	Monocrotophos	127	192		16	Dimepiperate	119	145		28	Mefenpyr‐diethyl	253	255	299
5	Dicloran (CNA)	206	208	176	17	Phenthoate (PAP)	274	246		29	Pyridaphenthion	340	199	188
6	Pyroquilon	173	130	172	18	Butachlor	176	237		30	Etoxazole	141	359	300
7	Phosphamidon	264	193		19	Imazamethabenz Methyl (Imazamethabenz-methyl)	144	245	256	31	Anilofos	125	334	184
8	δ-BHC	181	183	219	20	Uniconazole P	234	236		32	Tetradifon	159	229	356
9	Dimethenamid	154	230	203	21	Pretilachlor	162	238	262	33	Mefenacet	192	120
10	Tolclofos-methyl	265	267	125	22	Azaconazole	217	173	219	34	Halfenprox	263	265	183
11	Ametryn	227	212		23	Bupirimate	273	208	316	35	Tralomethrin**	181	253
12	Diethofencarb	225	267		24	(Z)-Pyriminobac-methyl	302	256	303	36	Imibenconazole	253	375

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
**Peak No. 35 is detected as Deltamethrin.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010 Ultra

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-5-1 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	Isoprocarb (MIPC)	121	136		13	(Z)-Dimethylvinphos	295	297		25	Fensulfothion	293	308
2	Propachlor	120	176		14	Tetraconazole	336	338		26	Mepronil	119	269	133
3	Chloropropham (Chloro IPC)	127	171	213	15	Bromophos	331	329		27	Benalaxyl	148	206	228
4	Cadusafos	159	158	114	16	Dimethametryn	212	255	71	28	Pyraflufen-ethyl	412	414	349
5	Pyrimethanil	198	199		17	Diclocymet	277	221		29	Thenylchlor	127	288	141
6	Terbacil	161	160	117	8	(E)-Pyrifenox	262	294	264	30	Zoxamide	187	189	258
6	Terbacil	161	160	117	8	(E)-Pyrifenox	262	294	264	30	Zoxamide	187	242
7	Iprobenfos (IBP)	204	246		19	Fenothiocarb	72	160		31	EPN	157	169	185
8	Benfuresate	163	121	256	20	Prothiofos	309	267		32	Bifenox	341	343	310
9	Acetochlor	146	162	223	21	Tricyclazole	189	118		33	Phosalone	182	121	367
10	Simetryne	213	155	170	22	Tribufos	169	202		34	Acrinathrin	181	289	208
11	Prometryn	241	184	226	23	Imibenconazole-debenzyl	235	270	128	35	Etofenprox	163	135
12	Esprocarb	222	162		24	Isoxathion	177	313		36	Flumiclorac‐pentyl	423	353	308
										37	Fluthiacet-methyl	403	405

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010 Ultra

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

PPL6-PPL10

Pesticide Mixture Standard Solution PL-6-3 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	XMC	122	107		11	Quinoclamine (ACN)	172	209		21	Flamprop‐methyl	105	276		31	Cyhalofop-butyl	256	357	229
2	Benfluralin (Bethrodine)	292	264	276	12	Cyanazine	225	240	198	22	Fenoxanil	189	293	328	32	Pyrazophos	221	232	373
3	Propazine	214	229	172	13	Nitrothal‐isopropyl	236	194	254	23	Oxadixyl	163	132	233	33	Cafenstrole	100	188
4	Cyanophos (CYAP)	109	243	125	14	Diphenamid	167	239	165	24	Edifenphos (EDDP)	173	201	310	34	Flumioxazin	354	287	355
5	Prohydrojasmon	153	184		15	(Z)-Pyrifenox	262	294	264	25	Trifloxystrobin	116	131	222	35	Tolfenpyrad	383	385
6	Benoxacor	120	259	176	16	Quinalphos	146	157	298	26	Diclofop‐methyl	340	253	281
7	Dichlofenthion (ECP)	279	223	162	17	Paclobutrazol	236	238	138	27	Pyributicarb	165	108	181
8	Bromobutide	119	232		18	Napropamide	128	100		28	Piperophos	122	140
9	Mefenoxam (Metalaxyl M)	206	249	234	19	Butamifos	286	200		29	Tebufenpyrad	318	276	333
10	Bromacil	205	190		20	Hexaconazole	214	216	231	30	Phenothrin	123	183

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-7-2 (each 20μg/ml Acetonitrile Solution)

LC/MS/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode
Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode
1	Thiamethoxam	292.2	210.9	+	11	(E)-Ferimzone	255.2	91.1	+	21	Fenoxycarb	302.3	116.0	+
2	Clothianidin	250.2	131.9	+	12	(Z)-Ferimzone	255.2	91.1	+	22	Anilofos	368.2	124.9	+
3	Chloridazon (PAC)	222.2	104.0	+	13	Methoxyphenozide	369.2	149.0	+	23	Cyflufenamid	413.1	295.0	+
4	Thiacloprid	253.1	126.0	+	14	Iprovalicarb	321.2	119.1	+	24	Pyrazolynate (Pyrazolate)	439.0	172.9	+
5	Thiabendazole	202.2	175.0	+	15	Chromafenozide	395.4	175.0	+	25	Indoxacarb (Indoxacarb-MP)	528.2	150.0	+
6	Azamethiphos	325.0	182.9	+	16	Butafenacil	492.1	330.9	+	26	Benzofenap	431.1	105.0	+
7	Dimethirimol	210.2	71.1	+	17	Simeconazole	294.2	70.0	+	27	Furathiocarb	383.2	195.0	+
8	Isoxaflutole	360.1	250.9	+	18	Oryzalin	347.1	304.9	+	28	Cloquintocet-mexyl	336.3	237.9	+
9	Azinphos-methyl	318.0	132.1	+	19	Cyazofamid	325.0	108.0	+	29	Abamectin B1a (Abamectin)	890.6	305.2	+
10	Pyriftalid	319.1	139.0	+	20	Naproanilide	292.2	171.0	+

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu LCMS-8040

[HPLC]

Column： Wakopak^® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm

Column temperature： 40 ℃

Eluent： A) 5 mmol/L CH₃COONH₄ in H₂O,　B) 5 mmol/L CH₃COONH₄ in CH₃OH

Gradient：

Time (min)	B conc. (%)
0-1	15-40
1-3.5	40
3.5-6	40-50
6-8	50-55
8-17.5	55-95
17.5-30	95
30-40	95-15

Flow rate： 0.2 mL/min

[MS]

Ionization： ESI

Mode： MRM

Pesticide Mixture Standard Solution PL-8-1 (each 20μg/mL Acetonitrile Solution)

LC/MS/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode
Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode
1	Flumetsulam	326.2	128.9	+	12	1-Naphthaleneacetic Acid	185.2	141.2	−
2	Thifensulfuron-methyl	388.2	167.0	+	13	Cloprop	199.2	127.1	−
3	Florasuram	360.1	128.9	+	14	Ioxynil	369.8	127.0	−
4	Cloransulam-methyl (Cloransulam methyl)	430.2	397.9	+	15	Triclopyr	253.9	196.1	−
5	Diclosulam	406.0	160.9	+	16	Mecoprop (MCPP)	213.1	141.1	−
6	Thidiazuron	221.1	102.0	+	17	Dichlorprop	233.0	161.1	−
7	Forchlorfenuron	248.1	128.9	+	18	MCPB	227.1	141.1	−
8	Gibberellin (Gibberellin A3)	345.1	143.2	−	19	Acifluorfen	360.2	316.2	−
9	Fluroxypyr	253.0	195.0	−	20	Fomesafen	436.9	195.2	−
10	4-Chlorophenoxyacetic Acid (4-CPA)	185.2	127.1	−	21	Haloxyfop	356.0	288.2	−
11	Bromoxynil	275.9	81.0	−

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu LCMS-8040

[HPLC]

Column： Wakopak^® Wakosil-Ⅱ 3C18HG 2.0 ×150 mm

Column temperature： 40 ℃

Eluent： A) 5 mmol/L CH₃COONH₄ in H₂O,　B) 5 mmol/L CH₃COONH₄ in CH₃OH

Gradient：

Time (min)	B conc. (%)
0-1	15-40
1-3.5	40
3.5-6	40-50
6-8	50-55
8-17.5	55-95
17.5-30	95
30-40	95-15

Flow rate： 0.2 mL/min

[MS]

Ionization： ESI

Mode： MRM

Pesticide Mixture Standard Solution PL-9-2 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	EPTC	128	132	189	10	Famphur	218	217	125
2	Etridiazole (Echlomezol)	211	183	246	11	Endosulfan Sulfate (Benzoepin Sulfate)	272	387	422
3	Chloroneb	191	193	206	12	Piperonyl Butoxide	176	177
4	Fenobucarb (BPMC)	121	150		13	Bioresmethrin	123	171	143
5	Diphenylamine	169	168	167	14	Iprodione	314	316
6	Propetamphos	138	236	194	15	Iprodione Metabolite	329	331
7	Pirimicarb	166	238		16	Fenoxaprop-ethyl	288	361	261
8	Imazalil	215	217	173	17	Prochloraz	180	308	266
9	Flusilazole	233	206	315

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-10-1 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	Aldicarb(deg.)	68	115	100	6	Carbaryl (NAC)	144	115	116
2	Aldoxycarb (Aldicarb sulfone) (deg.)	68	80		7	Metalaxyl	206	249
3	Acephate	136	94		8	Thiabendazole	201	174
4	Bendiocarb	151	166	223	9	Azoxystrobin	344	388
5	Metribuzin	198	144

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010 Ultra

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm×30 m

Column temperature： 50 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.3 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

PPL11-PPL15

Pesticide Mixture Solution PL-11-2 in Hexane 20 ug/ml

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	Hexachlorobenzene	286	249		9	cis-Chlordane (α-Chlordane)	375	272
2	Heptachlor	337	274		10	Dieldrin	277	261
3	Aldrin	265	261	293	11	p,p'-DDE	318
4	Dicofol(Kelthane) (deg.) [DCBP]	250			12	Endrin	317	345	245
5	Heptachlor Epoxide (isomer A)	351			13	p,p'-DDD	237	165
6	Oxychlordane	389			14	o,p'-DDT	237	165
7	Heptachlor Epoxide (isomer B)	351			15	p,p'-DDT	237	165	212
8	trans-Chlordane (γ-Chlordane)	375	272

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010

[GC]

Column： Rtx-5MS　0.25 μm, 0.32 mm × 30 m

Column temperature： 50 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-12-1 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	Chlorethoxyfos	153	263		11	Mecarbam	111	153		21	Carfentrazone-ethyl	312	340	330
2	Dicrotophos	127	193	237	12	Methoprene	131	159		22	Epoxiconazole	192	138	165
3	Phorate	75	121	260	13	Bromophos-ethyl	359	303		23	Picolinafen	376	238
4	Clomazone	125	204		14	Propaphos	220	304		24	Fenamidone	238	268
5	Isazofos	161	257	172	15	Chlorbenside	125	127	268	25	Spirodiclofen	312	259
6	Disulfoton (Ethylthiomethon)	88	274		16	Flutriafol	123	164	219	26	Cinidon-ethyl	330	358
7	Formothion	125	125		17	Chlorofenson (CPCBS)	111	175	302
8	Fenchlorphos	285	287		18	Carboxin	143	235
9	Ethofumesate	207	161	286	19	1,1-Dichloro-2,2-bis (4-ethylphenyl) ethane	223	224	167
10	2-(1-Naphthyl) acetamide(1-Naphthylacetamide)	141	185		20	Flufenpyr-ethyl	408	335

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010

[GC]

Column： BPX5　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (5 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-13-1 (each 20μg/ml Acetone Solution)

GC/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)			Peak No.	Constituent	Monitoring Ions (m/z)
1	Nitrapyrin	194	196		9	Resmethrin	123	171
2	Methacrifos	208	180	240	10	Furathiocarb	163	194
3	Tebuthiuron	156	171		11	Triticonazole	235	237	299
4	Oxabetrinil	73	77	103	12	Boscalid	140	342	344
5	S-Metolachlor	162	238		13	Thiacloprid	251	101
6	Flufenacet	151	211		14	Famoxadone	330	196	197
7	Triflumizole	206	278		15	Propaquizafop	443	299
8	Azamethiphos	215	217	324

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu QP-2010 Ultra

[GC]

Column： BPX5　0.25 μm, 0.32 mm×30 m

Column temperature： 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (5 min)

Injection temperature： 260 ℃

Carrier gas： He 2.2 mL/min

Splitless： 1 min

[MS]

Ionization： EI

Interface temperature： 280 ℃

Pesticide Mixture Standard Solution PL-14-2 (each 20μg/ml Acetonitrile Solution)

LC/MS/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent		Monitoring Ions (m/z)		Mode
Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent		Precursor	Product	Mode
1	Methomyl	163.1	88.0	+	11	Acibenzolar-S-methyl	211.0	135.9	+	21	Pencycuron		329.2	125.0	+
2	Imidacloprid	256.1	175.0	+	12	Dymron (Daimuron)	269.2	151.0	+	22	Hexaflumuron		463.1	157.9	+
3	Oxycarboxin	268.1	174.9	+	13	Cumyluron	303.2	185.0	+	23	Cycloate		216.2	83.1	+
4	Bendiocarb	224.3	109.0	+	14	Chloroxuron	291.1	72.1	+	24	Pentoxazone		354.1	286.1	+
5	Thiodicarb	355.1	87.9	+	15	Mepanipyrim	224.3	106.0	+	25	Oxaziclomefone		376.1	190.0	+
6	Pirimicarb	239.2	72.0	+	16	Triticonazole	318.3	70.0	+	26	Fenoxaprop-ethyl		362.1	287.9	+
7	Methabenzthiazuron	222.1	165.0	+	17	Indanofan	341.1	175.0	+	27	Flufenoxuron		489.0	158.0	+
8	Furametpyr	334.1	156.9	+	18	Tetrachlorvinphos (CVMP)	366.9	127.0	+	28	Cycloprothrin		499.1	180.9	+
9	Azoxystrobin	404.1	372.0	+	19	Carpropamid	336.1	138.9	+	29	Spinosad**	(Spinosyn A)	732.4	142.1	+
10	Methiocarb	226.1	169.0	+	20	Imazalil	297.1	158.9	+	29	Spinosad**	(Spinosyn D)	746.6	142.0	+
										30	Silafluofen		426.2	287.0	+

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
**The preparation concentration is converted to 20 µg/mL as a total of Spinosyn A and Spinosyn D.

Analysis conditions

[ Instrument ]

Shimadzu LCMS-8040

[HPLC]

Column： Wakopak^® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm

Column temperature： 40 ℃

Eluent： A) 5 mmol/L CH₃COONH₄ in H₂O,　B) 5 mmol/L CH₃COONH₄ in CH₃OH

Gradient：

Time (min)	B conc. (%)
0-1	15-40
1-3.5	40
3.5-6	40-50
6-8	50-55
8-17.5	55-95
17.5-30	95
30-40	95-15

Flow rate： 0.2 mL/min

[MS]

Ionization： ESI

Mode： MRM

Pesticide Mixture Standard Solution PL-15-1 (each 20μg/mL Acetonitrile Solution)

LC/MS/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode
Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode
1	Aldoxycarb (Aldicarb sulfone)	240.0	86.1	+	11	Fenamidone	312.0	92.2	+	21	(Z)-Fenpyroximate	422.1	366.2	+
2	Oxamyl	237.0	72.0	+	12	Flufenacet	364.0	152.1	+	22	Hexythiazox	354.1	229.1	+
3	Aldicarb	208.0	116.1	+	13	Epoxiconazole	331.1	121.1	+	23	(E)-Fenpyroximate	422.1	366.2	+
4	Carbofuran	222.1	165.1	+	14	Diflubenzuron	328.0	158.2	+	24	Diuron (DCMU)	232.0	186.9	−
5	Tebuthiuron	229.1	172.3	+	15	Tebufenozide	353.1	297.2	+	25	Linuron	247.9	160.7	−
6	Carbaryl (NAC)	202.0	145.1	+	16	Cyprodinil	226.1	93.1	+	26	Boscalid	342.9	113.9	−
7	Monolinuron	215.1	126.2	+	17	Triflumuron	359.1	156.2	+	27	Novaluron	491.1	84.6	−
8	Fluridone	330.0	309.1	+	18	Clofentezine	304.0	138.1	+	28	Teflubenzuron	381.1	152.1	−
9	(E)-Dimetomorph**	389.0	302.1	+	19	Quizalofop-ethyl	373.1	299.0	+	29	Lufenuron	508.9	339.1	−
10	(Z)-Dimetomorph**	389.0	302.1	+	20	Propaquizafop	445.1	100.1	+

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
**The preparation concentration is converted to 20 µg/mL as a total of E and Z isomers.

Analysis conditions

[ Instrument ]

Shimadzu LCMS-8040

[HPLC]

Column： Wakopak^® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm

Column temperature： 40 ℃

Eluent： A) 5 mmol/L CH₃COONH₄ in H₂O,　B) 5 mmol/L CH₃COONH₄ in CH₃OH

Gradient：

Time (min)	B conc. (%)
0-1	15-40
1-3.5	40
3.5-6	40-50
6-8	50-55
8-17.5	55-95
17.5-30	95
30-30.01	95-15
30.01-40	15

Flow rate： 0.2 mL/min

[MS]

Ionization： ESI

Mode： MRM

PPL16-PPL17

Pesticide Mixture Standard Solution PL-16-2 (each 20μg/mL Acetonitrile Solution)

LC/MS/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode
Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode
1	Metsulfuron-methyl	382.1	167.0	+	11	Pyrazosulfuron-ethyl	415.1	182.0	+	21	Fluazifop	328.1	282.1	+
2	Azimsulfuron	425.1	182.0	+	12	Naptalam	292.1	144.0	+	22	Triflusulfuron-methyl	493.1	264.1	+
3	Cinosulfuron	414.1	183.0	+	13	Trifloxysulfuron	438.1	182.0	+	23	Bensulfuron-methyl	411.1	149.1	+
4	Sulfosulfuron	471.1	211.0	+	14	Iodosulfuron-methyl	508.1	166.9	+	24	Primisulfuron-methyl	469.0	254.0	+
5	Flazasulfuron	408.1	182.0	+	15	Metosulam	418.0	174.9	+	25	Cyclosulfamuron	422.1	217.9	+
6	Imazosulfuron	413.1	156.0	+	16	Penoxsulam	484.1	195.0	+	26	Fenhexamid	302.1	97.1	+
7	Propoxycarbazone**	399.1	199.0	+	17	Chlorimuron-ethyl	415.1	186.0	+	27	Halosulfuron-methyl	433.1	252.0	−
8	Triasulfuron	402.1	167.0	+	18	Ethoxysulfuron	399.1	261.0	+	28	2,4-D (2,4-PA)	218.9	161.0	−
9	Mesosulfuron-methyl	504.1	182.0	+	19	Prosulfuron	420.1	141.0	+	29	MCPA (MCP)	198.9	141.0	−
10	Ethametsulfuron-methyl	411.1	196.0	+	20	Clodinafop Acid	312.0	266.0	+	30	Sulfentrazone	384.9	307.0	−

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
**The preparation concentration is converted to 20 µg/mL as a free base.

Analysis conditions

[ Instrument ]

Shimadzu LCMS-8040

[HPLC]

Column： Wakopak^® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm

Column temperature： 40 ℃

Eluent： A) 5 mmol/L CH₃COONH₄ in H₂O,　B) 5 mmol/L CH₃COONH₄ in CH₃OH

Gradient：

Time (min)	B conc. (%)
0-1	25-40
1-3.5	40
3.5-6	40-50
6-8	50-55
8-17.5	55-95
17.5-30	95
30 -40	95-25

Flow rate ： 0.2 mL/min

[MS]

Ionization： ESI

Mode： MRM

Pesticide Mixture Standard Solution PL-17-2 (each 20μg/ml Acetonitrile Solution)

LC/MS/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode
Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode
1	Pymetrozine	218.1	105.1	+	11	Flamprop-methyl	336.1	105.1	+	21	Trifloxystrobin	409.1	186.1	+
2	3-OH Carbofuran (3-Hydroxycarbofuran)	255.1	163.1	+	12	Triflumizole Metabolite	295.1	73.1	+	22	Triflumizole	346.1	73.1	+
3	Cymoxanil	199.2	128.1	+	13	Prometryn	242.4	200.1	+	23	Benfuracarb	411.3	195.1	+
4	Carbetamide	237.2	188.1	+	14	Clodinafop-propargyl	350.1	266.1	+	24	Fluazuron	506.1	158.0	+
5	Bromacil	261.0	205.0	+	15	Carfentrazone-ethyl	411.5	365.5	+	25	Etoxazole	360.2	141.0	+
6	Oxabetrinil	233.1	87.1	+	16	Benalaxyl	326.1	148.1	+	26	Chlorfluazuron	540.1	383.0	+
7	Chlorbufam	224.1	172.0	+	17	Mefenpyr-diethyl	373.2	327.0	+	27	Amitraz	294.2	163.1	+
8	Ametryn	228.1	186.1	+	18	Pyraclostrobin	390.1	194.1	+	28	Carbosulfan	381.2	118.1	+
9	Pyrimethanil	200.1	107.1	+	19	Phoxim	299.1	129.1	+	29	Fenpropimorph	304.2	147.1	+
10	Barban	275.2	177.9	+	20	Pyrazophos	374.2	222.1	+

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.

Analysis conditions

[ Instrument ]

Shimadzu LCMS-8040

[HPLC]

Column： Wakopak^® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm

Column temperature： 40 ℃

Eluent： A) 5 mmol/L CH₃COONH₄ in H₂O,　B) 5 mmol/L CH₃COONH₄ in CH₃OH

Gradient：

Time (min)	B conc. (%)
0-1	15-40
1-3.5	40
3.5-6	40-50
6-8	50-55
8-17.5	55-95
17.5-30	95
30 -40	95-15

Flow rate： 0.2 mL/min

[MS]

Ionization： ESI

Mode： MRM

VPL1-VPL2

Veterinary Drug Mixture Standard Solution PL-1-3 (each 20μg/ml Methanol Solution)

LC/MS/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode
Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode
1	Lincomycin**	407.2	126.2	+	12	Dexamethasone	393.2	337.0	+
2	Sulfacetamide	215.1	155.9	+	13	Emamectin B1a	887.6	158.1	+
3	Danofloxacin**	358.2	82.0	+	14	Famphur	326.1	92.8	+
4	Clenbuterol **	277.1	203.0	+	15	Fenobucarb (BPMC)	208.2	95.0	+
5	Xylazine **	221.3	90.0	+	16	Temephos (Abate)	467.0	124.9	+
6	Pyrimethamine	249.1	176.9	+	17	Allethrin	303.2	135.1	+
7	Trichlorfon (DEP)	257.1	108.8	+	18	Monensin	688.4	125.1	+
8	Tilmicosin	869.5	174.0	+	19	Florfenicol	358.1	185.1	−
9	Tiamulin**	494.3	192.1	+	20	2-Acetylamino-5-nitro thiazole	186.2	139.1	−
10	Prednisolone	361.2	147.0	+	21	Clorsulon	380.0	344.0	−
11	Hydrocortisone	363.3	121.0	+

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
**The preparation concentration is converted to 20 µg/mL as a free base.

Analysis conditions

[ Instrument ]

Shimadzu LCMS-8040

[HPLC]

Column： Wakopak^® Wakosil-Ⅱ 3C18HG 3.0 × 150 mm

Column temperature： 40 ℃

Eluent： A) 0.1% HCOOH in H₂O,　B) 0.1% HCOOH in CH₃CN

Gradient：

Time (min)	B conc. (%)
0-35	1-100
35-40	100

Flow rate： 0.2 mL/min

[MS]

Ionization： ESI

Mode： MRM

Veterinary Drug Mixture Standard Solution PL-2-1 (each 20μg/ml Methanol Solution)

LC/MS/MS Chromatogram*

Peak No.	Constituent	Monitoring Ions (m/z)		Mode	Peak No.	Constituent	Monitoring Ions (m/z)		Mode
Peak No.	Constituent	Precursor	Product	Mode	Peak No.	Constituent	Precursor	Product	Mode
1	5-Propylsulfonyl-1H-benzimidazole-2-amine	240.1	133.1	+	13	Sulfachlorpyridazine**	286.2	156.9	+
2	Levamisole**	207.1	180.0	+	14	Sulfadoxine	311.1	155.9	+
3	Thiabendazole	202.2	174.9	+	15	Sulfamethoxazole	254.1	156.0	+
4	Trimethoprim	291.2	230.0	+	16	Ethopabate	238.3	136.0	+
5	Sulfadiazine	251.1	155.9	+	17	Sulfadimethoxine	311.1	156.0	+
6	Ormetoprim	275.2	123.1	+	18	Sulfaquinoxaline**	301.1	156.0	+
7	Sulfathiazole	256.1	155.9	+	19	β-Trenbolone	271.2	199.0	+
8	Sulfapyridine	250.1	156.0	+	20	α-Trenbolone	271.2	199.0	+
9	Sulfamerazine	265.1	92.1	+	21	Melengestrol Acetate	397.3	279.0	+
10	Sulfadimidine	279.1	92.1	+	22	Thiamphenicol	356.1	185.1	−
11	Sulfamethoxypyridazine	281.1	156.1	+	23	Zeranol	321.3	277.4	−
12	Sulfamonomethoxine	281.1	156.0	+	24	Sulfanitran	334.0	136.1	−

*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
**The preparation concentration is converted to 20 µg/mL as a free base.

Analysis conditions

[ Instrument ]

Shimadzu LCMS-8040

[HPLC]

Column： Wakopak^® Wakosil-Ⅱ 3C18HG 3.0 × 150mm

Column temperature： 40 ℃

Eluent： A) 0.1% HCOOH in H₂O,　B) 0.1% HCOOH in CH₃CN

Gradient：

Time (min)	B conc. (%)
0-35	1-100
35-40	100

Flow rate： 0.2 mL/min

[MS]

Ionization： ESI

Mode： MRM

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Mixture Standard of Pesticides

Veterinary Drug Mixture Standard Solutions

Veterinary Drug Mixture Standard Solutions by Drug Classification

Author: T. Miura

For research use or further manufacturing use only. Not for use in diagnostic procedures.

Product content may differ from the actual image due to minor specification changes etc.

If the revision of product standards and packaging standards has been made, there is a case where the actual product specifications and images are different.