JP Food Sanitation Law "Positive List" for Pesticide Residue
FUJIFILM Wako offers over 1100 standard products ((certified reference material (CRM), single standards and standard mixture solutions)) for the "positive list" in Japan. Our CRM and standard products are highly purified based on our purification technology. The purity of almost all products is determined by qNMR. The high-quality standard products are essential for making chromatographic measurements and their assured values are important for final analytical results. qNMR using reference standards with traceability to the International System of Units (SI) recently attracts attention as one of absolute purity determining methods for standards for chromatography, because of its efficiency and reliability. In fact, qNMR has been used as the official analytical method regarding the Japanese Pharmacopoeia, Japanese Standards for Food Additives, and the Japanese Industrial Standard. We started to establish a supply system for standard products with absolute purity values determined by qNMR. We explored an appropriate framework for sample preparation procedures, NMR parameter sets, sample distribution ways and selection of target signal(s) of each compound. As a result, we found that qNMR was able to determine the purity of normal small molecular organic compounds with the accuracy of less than or equal to 1%. We established a supply system for standard products of very high purity such as pesticides, catechins, amino acids, natural toxins (e.g. mycotoxin), dietary supplements, and functional compounds.
PPL1-PPL5
Pesticide Mixture Standard Solution PL-1-2 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Omethoate | 156 | 110 | 141 | 11 | Malathion (Malathon) | 173 | 158 | 21 | Pyrethrin I, II | 123 | 133 | 162 | |
107 | 133 | 160 | ||||||||||||
2 | Trifluralin | 306 | 264 | 12 | Fenpropimorph | 128 | 129 | 303 | 22 | Norflurazon | 145 | 303 | 173 | |
3 | Dimethoate | 87 | 125 | 13 | Pendimethalin | 252 | 281 | 23 | Diflufenican | 266 | 394 | |||
4 | Atrazine | 200 | 215 | 14 | Penconazole | 159 | 248 | 24 | Bifenthrin | 181 | 166 | |||
5 | Terbufos | 231 | 288 | 153 | 15 | Procymidone | 283 | 285 | 25 | Azinphos-methyl | 160 | 132 | ||
6 | Tefluthrin | 177 | 197 | 383 | 16 | Methidathion (DMTP) | 145 | 85 | 302 | 26 | Fenarimol | 139 | 330 | 251 |
7 | Spiroxamine | 100 | 126 | 17 | Fenamiphos | 303 | 217 | 27 | trans-Permethirn | 183 | 163 | |||
100 | 101 | 126 | ||||||||||||
8 | Chlorpyrifosmethyl | 286 | 288 | 18 | Oxadiazon | 175 | 302 | 344 | 28 | cis-Permethirn | 183 | 163 | ||
9 | Terbutryn | 226 | 241 | 19 | Kresoxim-methyl | 116 | 206 | 29 | Cyfluthrin | 163 | 226 | 206 | ||
10 | Thiobencarb (Benthiocarb) | 100 | 257 | 20 | Chlorfenapyr | 364 | 328 | 30 | Flucythrinate | 199 | 451 | |||
31 | Fluvalinate | 250 | 252 |
-
*Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010 Ultra
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-2-1 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Propoxur (PHC) | 110 | 152 | 11 | Isofenphos Oxon | 229 | 314 | 21 | Propiconazole | 173 | 259 | |||
2 | Carbofuran | 164 | 149 | 12 | Chlorfenvinphos(α-CVP, β-CVP) | 267 | 323 | 22 | Hexazinone | 171 | 252 | 128 | ||
3 | Quintozene (PCNB) | 237 | 295 | 13 | Isofenphos | 213 | 255 | 23 | Propargite (BPPS) | 173 | 150 | |||
4 | Propyzamide | 173 | 255 | 14 | Triadimenol | 112 | 168 | 24 | Phosmet (PMP) | 160 | 161 | 133 | ||
5 | Tri-allate | 268 | 128 | 15 | Tetrachlorvinphos (CVMP) | 329 | 331 | 25 | Methoxychlor | 227 | 274 | 228 | ||
6 | Vinclozolin | 285 | 212 | 16 | Isoprothiolane | 118 | 290 | 26 | Pyriproxyfen | 136 | 226 | |||
7 | Alachlor | 160 | 188 | 17 | Myclobutanil | 179 | 150 | 27 | Pyraclofos | 360 | 194 | |||
8 | Fenitrothion (MEP) | 277 | 260 | 18 | Buprofezin | 105 | 172 | 28 | Fluquinconazole | 340 | 108 | |||
9 | Metolachlor | 162 | 238 | 19 | Cyproconazole | 222 | 139 | 29 | Fenbuconazole | 129 | 198 | |||
10 | Fenthion (MPP) | 278 | 169 | 20 | Ethion | 231 | 384 | 30 | Fluridone | 328 | 329 | |||
31 | Difenoconazole | 323 | 265 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010 Ultra
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-3-3 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Ethoprophos | 158 | 200 | 139 | 11 | Fipronil | 367 | 369 | 351 | 21 | Fenpropathrin | 181 | 265 | 349 |
2 | Simazine (CAT) | 201 | 173 | 12 | Flutolanil | 173 | 323 | 22 | Cyhalothrin | 181 | 197 | 208 | ||
3 | Diazinon | 137 | 152 | 304 | 13 | Profenofos | 139 | 337 | 374 | 23 | Bitertanol | 170 | 168 | 112 |
4 | Propanil (DCPA) | 161 | 217 | 14 | Oxyfluorfen | 252 | 361 | 300 | 24 | Pyridaben | 147 | 309 | ||
5 | Parathion-methyl (Methylparathion) | 125 | 233 | 263 | 15 | Chlorobenzilate | 139 | 251 | 25 | Cypermethrin | 163 | 181 | 165 | |
6 | Pirimiphos-methyl | 290 | 276 | 305 | 16 | Triazophos | 161 | 257 | 26 | Fenvalerate | 125 | 419 | 225 | |
7 | Chlorpyrifos | 197 | 286 | 314 | 17 | Quinoxyfen | 237 | 272 | 307 | 27 | Deltamethrin | 181 | 253 | |
8 | Parathion | 291 | 235 | 18 | Tebuconazole | 125 | 250 | |||||||
9 | Triadimefon | 208 | 181 | 19 | Acetamiprid | 166 | 221 | |||||||
10 | Allethrin | 123 | 136 | 20 | Bromopropylate (Phenisobromolate) | 341 | 183 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010 Ultra
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-4-2 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Mevinphos ( (E)-Mevinphos, (Z)-Mevinphos) |
127 | 109 | 192 | 13 | Chlorthal-dimethyl (TCTP) | 301 | 299 | 332 | 25 | Fluacrypyrim | 145 | 320 | 189 |
2 | Tecnazene | 203 | 215 | 261 | 14 | Fthalide | 243 | 241 | 272 | 26 | Lenacil | 153 | 154 | 110 |
3 | Ethalfluralin | 276 | 316 | 15 | Fosthiazate | 139 | 166 | 283 | 27 | (E)-Pyriminobac-methyl | 302 | 256 | 303 | |
4 | Monocrotophos | 127 | 192 | 16 | Dimepiperate | 119 | 145 | 28 | Mefenpyr‐diethyl | 253 | 255 | 299 | ||
5 | Dicloran (CNA) | 206 | 208 | 176 | 17 | Phenthoate (PAP) | 274 | 246 | 29 | Pyridaphenthion | 340 | 199 | 188 | |
6 | Pyroquilon | 173 | 130 | 172 | 18 | Butachlor | 176 | 237 | 30 | Etoxazole | 141 | 359 | 300 | |
7 | Phosphamidon | 264 | 193 | 19 | Imazamethabenz Methyl (Imazamethabenz-methyl) | 144 | 245 | 256 | 31 | Anilofos | 125 | 334 | 184 | |
8 | δ-BHC | 181 | 183 | 219 | 20 | Uniconazole P | 234 | 236 | 32 | Tetradifon | 159 | 229 | 356 | |
9 | Dimethenamid | 154 | 230 | 203 | 21 | Pretilachlor | 162 | 238 | 262 | 33 | Mefenacet | 192 | 120 | |
10 | Tolclofos-methyl | 265 | 267 | 125 | 22 | Azaconazole | 217 | 173 | 219 | 34 | Halfenprox | 263 | 265 | 183 |
11 | Ametryn | 227 | 212 | 23 | Bupirimate | 273 | 208 | 316 | 35 | Tralomethrin** | 181 | 253 | ||
12 | Diethofencarb | 225 | 267 | 24 | (Z)-Pyriminobac-methyl | 302 | 256 | 303 | 36 | Imibenconazole | 253 | 375 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
- **Peak No. 35 is detected as Deltamethrin.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010 Ultra
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-5-1 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Isoprocarb (MIPC) | 121 | 136 | 13 | (Z)-Dimethylvinphos | 295 | 297 | 25 | Fensulfothion | 293 | 308 | |||
2 | Propachlor | 120 | 176 | 14 | Tetraconazole | 336 | 338 | 26 | Mepronil | 119 | 269 | 133 | ||
3 | Chloropropham (Chloro IPC) | 127 | 171 | 213 | 15 | Bromophos | 331 | 329 | 27 | Benalaxyl | 148 | 206 | 228 | |
4 | Cadusafos | 159 | 158 | 114 | 16 | Dimethametryn | 212 | 255 | 71 | 28 | Pyraflufen-ethyl | 412 | 414 | 349 |
5 | Pyrimethanil | 198 | 199 | 17 | Diclocymet | 277 | 221 | 29 | Thenylchlor | 127 | 288 | 141 | ||
6 | Terbacil | 161 | 160 | 117 | 8 | (E)-Pyrifenox | 262 | 294 | 264 | 30 | Zoxamide | 187 | 189 | 258 |
187 | 242 | |||||||||||||
7 | Iprobenfos (IBP) | 204 | 246 | 19 | Fenothiocarb | 72 | 160 | 31 | EPN | 157 | 169 | 185 | ||
8 | Benfuresate | 163 | 121 | 256 | 20 | Prothiofos | 309 | 267 | 32 | Bifenox | 341 | 343 | 310 | |
9 | Acetochlor | 146 | 162 | 223 | 21 | Tricyclazole | 189 | 118 | 33 | Phosalone | 182 | 121 | 367 | |
10 | Simetryne | 213 | 155 | 170 | 22 | Tribufos | 169 | 202 | 34 | Acrinathrin | 181 | 289 | 208 | |
11 | Prometryn | 241 | 184 | 226 | 23 | Imibenconazole-debenzyl | 235 | 270 | 128 | 35 | Etofenprox | 163 | 135 | |
12 | Esprocarb | 222 | 162 | 24 | Isoxathion | 177 | 313 | 36 | Flumiclorac‐pentyl | 423 | 353 | 308 | ||
37 | Fluthiacet-methyl | 403 | 405 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010 Ultra
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
PPL6-PPL10
Pesticide Mixture Standard Solution PL-6-3 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | XMC | 122 | 107 | 11 | Quinoclamine (ACN) | 172 | 209 | 21 | Flamprop‐methyl | 105 | 276 | 31 | Cyhalofop-butyl | 256 | 357 | 229 | |||
2 | Benfluralin (Bethrodine) | 292 | 264 | 276 | 12 | Cyanazine | 225 | 240 | 198 | 22 | Fenoxanil | 189 | 293 | 328 | 32 | Pyrazophos | 221 | 232 | 373 |
3 | Propazine | 214 | 229 | 172 | 13 | Nitrothal‐isopropyl | 236 | 194 | 254 | 23 | Oxadixyl | 163 | 132 | 233 | 33 | Cafenstrole | 100 | 188 | |
4 | Cyanophos (CYAP) | 109 | 243 | 125 | 14 | Diphenamid | 167 | 239 | 165 | 24 | Edifenphos (EDDP) | 173 | 201 | 310 | 34 | Flumioxazin | 354 | 287 | 355 |
5 | Prohydrojasmon | 153 | 184 | 15 | (Z)-Pyrifenox | 262 | 294 | 264 | 25 | Trifloxystrobin | 116 | 131 | 222 | 35 | Tolfenpyrad | 383 | 385 | ||
6 | Benoxacor | 120 | 259 | 176 | 16 | Quinalphos | 146 | 157 | 298 | 26 | Diclofop‐methyl | 340 | 253 | 281 | |||||
7 | Dichlofenthion (ECP) | 279 | 223 | 162 | 17 | Paclobutrazol | 236 | 238 | 138 | 27 | Pyributicarb | 165 | 108 | 181 | |||||
8 | Bromobutide | 119 | 232 | 18 | Napropamide | 128 | 100 | 28 | Piperophos | 122 | 140 | ||||||||
9 | Mefenoxam (Metalaxyl M) | 206 | 249 | 234 | 19 | Butamifos | 286 | 200 | 29 | Tebufenpyrad | 318 | 276 | 333 | ||||||
10 | Bromacil | 205 | 190 | 20 | Hexaconazole | 214 | 216 | 231 | 30 | Phenothrin | 123 | 183 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-7-2 (each 20μg/ml Acetonitrile Solution)
LC/MS/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | |||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Precursor | Product | Precursor | Product | Precursor | Product | |||||||||
1 | Thiamethoxam | 292.2 | 210.9 | + | 11 | (E)-Ferimzone | 255.2 | 91.1 | + | 21 | Fenoxycarb | 302.3 | 116.0 | + |
2 | Clothianidin | 250.2 | 131.9 | + | 12 | (Z)-Ferimzone | 255.2 | 91.1 | + | 22 | Anilofos | 368.2 | 124.9 | + |
3 | Chloridazon (PAC) | 222.2 | 104.0 | + | 13 | Methoxyphenozide | 369.2 | 149.0 | + | 23 | Cyflufenamid | 413.1 | 295.0 | + |
4 | Thiacloprid | 253.1 | 126.0 | + | 14 | Iprovalicarb | 321.2 | 119.1 | + | 24 | Pyrazolynate (Pyrazolate) | 439.0 | 172.9 | + |
5 | Thiabendazole | 202.2 | 175.0 | + | 15 | Chromafenozide | 395.4 | 175.0 | + | 25 | Indoxacarb (Indoxacarb-MP) | 528.2 | 150.0 | + |
6 | Azamethiphos | 325.0 | 182.9 | + | 16 | Butafenacil | 492.1 | 330.9 | + | 26 | Benzofenap | 431.1 | 105.0 | + |
7 | Dimethirimol | 210.2 | 71.1 | + | 17 | Simeconazole | 294.2 | 70.0 | + | 27 | Furathiocarb | 383.2 | 195.0 | + |
8 | Isoxaflutole | 360.1 | 250.9 | + | 18 | Oryzalin | 347.1 | 304.9 | + | 28 | Cloquintocet-mexyl | 336.3 | 237.9 | + |
9 | Azinphos-methyl | 318.0 | 132.1 | + | 19 | Cyazofamid | 325.0 | 108.0 | + | 29 | Abamectin B1a (Abamectin) | 890.6 | 305.2 | + |
10 | Pyriftalid | 319.1 | 139.0 | + | 20 | Naproanilide | 292.2 | 171.0 | + |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu LCMS-8040
[HPLC]
Column: Wakopak® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm
Column temperature: 40 ℃
Eluent: A) 5 mmol/L CH3COONH4 in H2O, B) 5 mmol/L CH3COONH4 in CH3OH
Gradient:
Time (min) | B conc. (%) |
---|---|
0-1 | 15-40 |
1-3.5 | 40 |
3.5-6 | 40-50 |
6-8 | 50-55 |
8-17.5 | 55-95 |
17.5-30 | 95 |
30-40 | 95-15 |
Flow rate: 0.2 mL/min
[MS]
Ionization: ESI
Mode: MRM
Pesticide Mixture Standard Solution PL-8-1 (each 20μg/mL Acetonitrile Solution)
LC/MS/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | ||
---|---|---|---|---|---|---|---|---|---|
Precursor | Product | Precursor | Product | ||||||
1 | Flumetsulam | 326.2 | 128.9 | + | 12 | 1-Naphthaleneacetic Acid | 185.2 | 141.2 | − |
2 | Thifensulfuron-methyl | 388.2 | 167.0 | + | 13 | Cloprop | 199.2 | 127.1 | − |
3 | Florasuram | 360.1 | 128.9 | + | 14 | Ioxynil | 369.8 | 127.0 | − |
4 | Cloransulam-methyl (Cloransulam methyl) |
430.2 | 397.9 | + | 15 | Triclopyr | 253.9 | 196.1 | − |
5 | Diclosulam | 406.0 | 160.9 | + | 16 | Mecoprop (MCPP) | 213.1 | 141.1 | − |
6 | Thidiazuron | 221.1 | 102.0 | + | 17 | Dichlorprop | 233.0 | 161.1 | − |
7 | Forchlorfenuron | 248.1 | 128.9 | + | 18 | MCPB | 227.1 | 141.1 | − |
8 | Gibberellin (Gibberellin A3) | 345.1 | 143.2 | − | 19 | Acifluorfen | 360.2 | 316.2 | − |
9 | Fluroxypyr | 253.0 | 195.0 | − | 20 | Fomesafen | 436.9 | 195.2 | − |
10 | 4-Chlorophenoxyacetic Acid (4-CPA) |
185.2 | 127.1 | − | 21 | Haloxyfop | 356.0 | 288.2 | − |
11 | Bromoxynil | 275.9 | 81.0 | − |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu LCMS-8040
[HPLC]
Column: Wakopak® Wakosil-Ⅱ 3C18HG 2.0 ×150 mm
Column temperature: 40 ℃
Eluent: A) 5 mmol/L CH3COONH4 in H2O, B) 5 mmol/L CH3COONH4 in CH3OH
Gradient:
Time (min) | B conc. (%) |
---|---|
0-1 | 15-40 |
1-3.5 | 40 |
3.5-6 | 40-50 |
6-8 | 50-55 |
8-17.5 | 55-95 |
17.5-30 | 95 |
30-40 | 95-15 |
Flow rate: 0.2 mL/min
[MS]
Ionization: ESI
Mode: MRM
Pesticide Mixture Standard Solution PL-9-2 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||
---|---|---|---|---|---|---|---|---|---|
1 | EPTC | 128 | 132 | 189 | 10 | Famphur | 218 | 217 | 125 |
2 | Etridiazole (Echlomezol) | 211 | 183 | 246 | 11 | Endosulfan Sulfate (Benzoepin Sulfate) | 272 | 387 | 422 |
3 | Chloroneb | 191 | 193 | 206 | 12 | Piperonyl Butoxide | 176 | 177 | |
4 | Fenobucarb (BPMC) | 121 | 150 | 13 | Bioresmethrin | 123 | 171 | 143 | |
5 | Diphenylamine | 169 | 168 | 167 | 14 | Iprodione | 314 | 316 | |
6 | Propetamphos | 138 | 236 | 194 | 15 | Iprodione Metabolite | 329 | 331 | |
7 | Pirimicarb | 166 | 238 | 16 | Fenoxaprop-ethyl | 288 | 361 | 261 | |
8 | Imazalil | 215 | 217 | 173 | 17 | Prochloraz | 180 | 308 | 266 |
9 | Flusilazole | 233 | 206 | 315 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-10-1 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||
---|---|---|---|---|---|---|---|---|---|
1 | Aldicarb(deg.) | 68 | 115 | 100 | 6 | Carbaryl (NAC) | 144 | 115 | 116 |
2 | Aldoxycarb (Aldicarb sulfone) (deg.) | 68 | 80 | 7 | Metalaxyl | 206 | 249 | ||
3 | Acephate | 136 | 94 | 8 | Thiabendazole | 201 | 174 | ||
4 | Bendiocarb | 151 | 166 | 223 | 9 | Azoxystrobin | 344 | 388 | |
5 | Metribuzin | 198 | 144 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010 Ultra
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm×30 m
Column temperature: 50 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.3 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
PPL11-PPL15
Pesticide Mixture Solution PL-11-2 in Hexane 20 ug/ml
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||
---|---|---|---|---|---|---|---|---|---|
1 | Hexachlorobenzene | 286 | 249 | 9 | cis-Chlordane (α-Chlordane) | 375 | 272 | ||
2 | Heptachlor | 337 | 274 | 10 | Dieldrin | 277 | 261 | ||
3 | Aldrin | 265 | 261 | 293 | 11 | p,p'-DDE | 318 | ||
4 | Dicofol(Kelthane) (deg.) [DCBP] | 250 | 12 | Endrin | 317 | 345 | 245 | ||
5 | Heptachlor Epoxide (isomer A) | 351 | 13 | p,p'-DDD | 237 | 165 | |||
6 | Oxychlordane | 389 | 14 | o,p'-DDT | 237 | 165 | |||
7 | Heptachlor Epoxide (isomer B) | 351 | 15 | p,p'-DDT | 237 | 165 | 212 | ||
8 | trans-Chlordane (γ-Chlordane) | 375 | 272 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010
[GC]
Column: Rtx-5MS 0.25 μm, 0.32 mm × 30 m
Column temperature: 50 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (10 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-12-1 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | Chlorethoxyfos | 153 | 263 | 11 | Mecarbam | 111 | 153 | 21 | Carfentrazone-ethyl | 312 | 340 | 330 | ||
2 | Dicrotophos | 127 | 193 | 237 | 12 | Methoprene | 131 | 159 | 22 | Epoxiconazole | 192 | 138 | 165 | |
3 | Phorate | 75 | 121 | 260 | 13 | Bromophos-ethyl | 359 | 303 | 23 | Picolinafen | 376 | 238 | ||
4 | Clomazone | 125 | 204 | 14 | Propaphos | 220 | 304 | 24 | Fenamidone | 238 | 268 | |||
5 | Isazofos | 161 | 257 | 172 | 15 | Chlorbenside | 125 | 127 | 268 | 25 | Spirodiclofen | 312 | 259 | |
6 | Disulfoton (Ethylthiomethon) | 88 | 274 | 16 | Flutriafol | 123 | 164 | 219 | 26 | Cinidon-ethyl | 330 | 358 | ||
7 | Formothion | 125 | 125 | 17 | Chlorofenson (CPCBS) | 111 | 175 | 302 | ||||||
8 | Fenchlorphos | 285 | 287 | 18 | Carboxin | 143 | 235 | |||||||
9 | Ethofumesate | 207 | 161 | 286 | 19 | 1,1-Dichloro-2,2-bis (4-ethylphenyl) ethane | 223 | 224 | 167 | |||||
10 | 2-(1-Naphthyl) acetamide(1-Naphthylacetamide) | 141 | 185 | 20 | Flufenpyr-ethyl | 408 | 335 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010
[GC]
Column: BPX5 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (5 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-13-1 (each 20μg/ml Acetone Solution)
GC/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Peak No. | Constituent | Monitoring Ions (m/z) | ||||
---|---|---|---|---|---|---|---|---|---|
1 | Nitrapyrin | 194 | 196 | 9 | Resmethrin | 123 | 171 | ||
2 | Methacrifos | 208 | 180 | 240 | 10 | Furathiocarb | 163 | 194 | |
3 | Tebuthiuron | 156 | 171 | 11 | Triticonazole | 235 | 237 | 299 | |
4 | Oxabetrinil | 73 | 77 | 103 | 12 | Boscalid | 140 | 342 | 344 |
5 | S-Metolachlor | 162 | 238 | 13 | Thiacloprid | 251 | 101 | ||
6 | Flufenacet | 151 | 211 | 14 | Famoxadone | 330 | 196 | 197 | |
7 | Triflumizole | 206 | 278 | 15 | Propaquizafop | 443 | 299 | ||
8 | Azamethiphos | 215 | 217 | 324 |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu QP-2010 Ultra
[GC]
Column: BPX5 0.25 μm, 0.32 mm×30 m
Column temperature: 80 ℃ (1 min)→20 ℃/min→180 ℃→5 ℃/min→300 ℃ (5 min)
Injection temperature: 260 ℃
Carrier gas: He 2.2 mL/min
Splitless: 1 min
[MS]
Ionization: EI
Interface temperature: 280 ℃
Pesticide Mixture Standard Solution PL-14-2 (each 20μg/ml Acetonitrile Solution)
LC/MS/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | ||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Precursor | Product | Precursor | Product | Precursor | Product | ||||||||||
1 | Methomyl | 163.1 | 88.0 | + | 11 | Acibenzolar-S-methyl | 211.0 | 135.9 | + | 21 | Pencycuron | 329.2 | 125.0 | + | |
2 | Imidacloprid | 256.1 | 175.0 | + | 12 | Dymron (Daimuron) | 269.2 | 151.0 | + | 22 | Hexaflumuron | 463.1 | 157.9 | + | |
3 | Oxycarboxin | 268.1 | 174.9 | + | 13 | Cumyluron | 303.2 | 185.0 | + | 23 | Cycloate | 216.2 | 83.1 | + | |
4 | Bendiocarb | 224.3 | 109.0 | + | 14 | Chloroxuron | 291.1 | 72.1 | + | 24 | Pentoxazone | 354.1 | 286.1 | + | |
5 | Thiodicarb | 355.1 | 87.9 | + | 15 | Mepanipyrim | 224.3 | 106.0 | + | 25 | Oxaziclomefone | 376.1 | 190.0 | + | |
6 | Pirimicarb | 239.2 | 72.0 | + | 16 | Triticonazole | 318.3 | 70.0 | + | 26 | Fenoxaprop-ethyl | 362.1 | 287.9 | + | |
7 | Methabenzthiazuron | 222.1 | 165.0 | + | 17 | Indanofan | 341.1 | 175.0 | + | 27 | Flufenoxuron | 489.0 | 158.0 | + | |
8 | Furametpyr | 334.1 | 156.9 | + | 18 | Tetrachlorvinphos (CVMP) | 366.9 | 127.0 | + | 28 | Cycloprothrin | 499.1 | 180.9 | + | |
9 | Azoxystrobin | 404.1 | 372.0 | + | 19 | Carpropamid | 336.1 | 138.9 | + | 29 | Spinosad** | (Spinosyn A) | 732.4 | 142.1 | + |
10 | Methiocarb | 226.1 | 169.0 | + | 20 | Imazalil | 297.1 | 158.9 | + | (Spinosyn D) | 746.6 | 142.0 | + | ||
30 | Silafluofen | 426.2 | 287.0 | + |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
- **The preparation concentration is converted to 20 µg/mL as a total of Spinosyn A and Spinosyn D.
Analysis conditions
[ Instrument ]
Shimadzu LCMS-8040
[HPLC]
Column: Wakopak® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm
Column temperature: 40 ℃
Eluent: A) 5 mmol/L CH3COONH4 in H2O, B) 5 mmol/L CH3COONH4 in CH3OH
Gradient:
Time (min) | B conc. (%) |
---|---|
0-1 | 15-40 |
1-3.5 | 40 |
3.5-6 | 40-50 |
6-8 | 50-55 |
8-17.5 | 55-95 |
17.5-30 | 95 |
30-40 | 95-15 |
Flow rate: 0.2 mL/min
[MS]
Ionization: ESI
Mode: MRM
Pesticide Mixture Standard Solution PL-15-1 (each 20μg/mL Acetonitrile Solution)
LC/MS/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | ||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Precursor | Product | Precursor | Product | Precursor | Product | ||||||||||
1 | Aldoxycarb (Aldicarb sulfone) |
240.0 | 86.1 | + | 11 | Fenamidone | 312.0 | 92.2 | + | 21 | (Z)-Fenpyroximate | 422.1 | 366.2 | + | |
2 | Oxamyl | 237.0 | 72.0 | + | 12 | Flufenacet | 364.0 | 152.1 | + | 22 | Hexythiazox | 354.1 | 229.1 | + | |
3 | Aldicarb | 208.0 | 116.1 | + | 13 | Epoxiconazole | 331.1 | 121.1 | + | 23 | (E)-Fenpyroximate | 422.1 | 366.2 | + | |
4 | Carbofuran | 222.1 | 165.1 | + | 14 | Diflubenzuron | 328.0 | 158.2 | + | 24 | Diuron (DCMU) | 232.0 | 186.9 | − | |
5 | Tebuthiuron | 229.1 | 172.3 | + | 15 | Tebufenozide | 353.1 | 297.2 | + | 25 | Linuron | 247.9 | 160.7 | − | |
6 | Carbaryl (NAC) | 202.0 | 145.1 | + | 16 | Cyprodinil | 226.1 | 93.1 | + | 26 | Boscalid | 342.9 | 113.9 | − | |
7 | Monolinuron | 215.1 | 126.2 | + | 17 | Triflumuron | 359.1 | 156.2 | + | 27 | Novaluron | 491.1 | 84.6 | − | |
8 | Fluridone | 330.0 | 309.1 | + | 18 | Clofentezine | 304.0 | 138.1 | + | 28 | Teflubenzuron | 381.1 | 152.1 | − | |
9 | (E)-Dimetomorph** | 389.0 | 302.1 | + | 19 | Quizalofop-ethyl | 373.1 | 299.0 | + | 29 | Lufenuron | 508.9 | 339.1 | − | |
10 | (Z)-Dimetomorph** | 389.0 | 302.1 | + | 20 | Propaquizafop | 445.1 | 100.1 | + |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
- **The preparation concentration is converted to 20 µg/mL as a total of E and Z isomers.
Analysis conditions
[ Instrument ]
Shimadzu LCMS-8040
[HPLC]
Column: Wakopak® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm
Column temperature: 40 ℃
Eluent: A) 5 mmol/L CH3COONH4 in H2O, B) 5 mmol/L CH3COONH4 in CH3OH
Gradient:
Time (min) | B conc. (%) |
---|---|
0-1 | 15-40 |
1-3.5 | 40 |
3.5-6 | 40-50 |
6-8 | 50-55 |
8-17.5 | 55-95 |
17.5-30 | 95 |
30-30.01 | 95-15 |
30.01-40 | 15 |
Flow rate: 0.2 mL/min
[MS]
Ionization: ESI
Mode: MRM
PPL16-PPL17
Pesticide Mixture Standard Solution PL-16-2 (each 20μg/mL Acetonitrile Solution)
LC/MS/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | ||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Precursor | Product | Precursor | Product | Precursor | Product | ||||||||||
1 | Metsulfuron-methyl | 382.1 | 167.0 | + | 11 | Pyrazosulfuron-ethyl | 415.1 | 182.0 | + | 21 | Fluazifop | 328.1 | 282.1 | + | |
2 | Azimsulfuron | 425.1 | 182.0 | + | 12 | Naptalam | 292.1 | 144.0 | + | 22 | Triflusulfuron-methyl | 493.1 | 264.1 | + | |
3 | Cinosulfuron | 414.1 | 183.0 | + | 13 | Trifloxysulfuron | 438.1 | 182.0 | + | 23 | Bensulfuron-methyl | 411.1 | 149.1 | + | |
4 | Sulfosulfuron | 471.1 | 211.0 | + | 14 | Iodosulfuron-methyl | 508.1 | 166.9 | + | 24 | Primisulfuron-methyl | 469.0 | 254.0 | + | |
5 | Flazasulfuron | 408.1 | 182.0 | + | 15 | Metosulam | 418.0 | 174.9 | + | 25 | Cyclosulfamuron | 422.1 | 217.9 | + | |
6 | Imazosulfuron | 413.1 | 156.0 | + | 16 | Penoxsulam | 484.1 | 195.0 | + | 26 | Fenhexamid | 302.1 | 97.1 | + | |
7 | Propoxycarbazone** | 399.1 | 199.0 | + | 17 | Chlorimuron-ethyl | 415.1 | 186.0 | + | 27 | Halosulfuron-methyl | 433.1 | 252.0 | − | |
8 | Triasulfuron | 402.1 | 167.0 | + | 18 | Ethoxysulfuron | 399.1 | 261.0 | + | 28 | 2,4-D (2,4-PA) | 218.9 | 161.0 | − | |
9 | Mesosulfuron-methyl | 504.1 | 182.0 | + | 19 | Prosulfuron | 420.1 | 141.0 | + | 29 | MCPA (MCP) | 198.9 | 141.0 | − | |
10 | Ethametsulfuron-methyl | 411.1 | 196.0 | + | 20 | Clodinafop Acid | 312.0 | 266.0 | + | 30 | Sulfentrazone | 384.9 | 307.0 | − |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
- **The preparation concentration is converted to 20 µg/mL as a free base.
Analysis conditions
[ Instrument ]
Shimadzu LCMS-8040
[HPLC]
Column: Wakopak® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm
Column temperature: 40 ℃
Eluent: A) 5 mmol/L CH3COONH4 in H2O, B) 5 mmol/L CH3COONH4 in CH3OH
Gradient:
Time (min) | B conc. (%) |
---|---|
0-1 | 25-40 |
1-3.5 | 40 |
3.5-6 | 40-50 |
6-8 | 50-55 |
8-17.5 | 55-95 |
17.5-30 | 95 |
30 -40 | 95-25 |
Flow rate : 0.2 mL/min
[MS]
Ionization: ESI
Mode: MRM
Pesticide Mixture Standard Solution PL-17-2 (each 20μg/ml Acetonitrile Solution)
LC/MS/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | ||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Precursor | Product | Precursor | Product | Precursor | Product | ||||||||||
1 | Pymetrozine | 218.1 | 105.1 | + | 11 | Flamprop-methyl | 336.1 | 105.1 | + | 21 | Trifloxystrobin | 409.1 | 186.1 | + | |
2 | 3-OH Carbofuran (3-Hydroxycarbofuran) | 255.1 | 163.1 | + | 12 | Triflumizole Metabolite | 295.1 | 73.1 | + | 22 | Triflumizole | 346.1 | 73.1 | + | |
3 | Cymoxanil | 199.2 | 128.1 | + | 13 | Prometryn | 242.4 | 200.1 | + | 23 | Benfuracarb | 411.3 | 195.1 | + | |
4 | Carbetamide | 237.2 | 188.1 | + | 14 | Clodinafop-propargyl | 350.1 | 266.1 | + | 24 | Fluazuron | 506.1 | 158.0 | + | |
5 | Bromacil | 261.0 | 205.0 | + | 15 | Carfentrazone-ethyl | 411.5 | 365.5 | + | 25 | Etoxazole | 360.2 | 141.0 | + | |
6 | Oxabetrinil | 233.1 | 87.1 | + | 16 | Benalaxyl | 326.1 | 148.1 | + | 26 | Chlorfluazuron | 540.1 | 383.0 | + | |
7 | Chlorbufam | 224.1 | 172.0 | + | 17 | Mefenpyr-diethyl | 373.2 | 327.0 | + | 27 | Amitraz | 294.2 | 163.1 | + | |
8 | Ametryn | 228.1 | 186.1 | + | 18 | Pyraclostrobin | 390.1 | 194.1 | + | 28 | Carbosulfan | 381.2 | 118.1 | + | |
9 | Pyrimethanil | 200.1 | 107.1 | + | 19 | Phoxim | 299.1 | 129.1 | + | 29 | Fenpropimorph | 304.2 | 147.1 | + | |
10 | Barban | 275.2 | 177.9 | + | 20 | Pyrazophos | 374.2 | 222.1 | + |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
Analysis conditions
[ Instrument ]
Shimadzu LCMS-8040
[HPLC]
Column: Wakopak® Wakosil-Ⅱ 3C18HG 2.0 × 150 mm
Column temperature: 40 ℃
Eluent: A) 5 mmol/L CH3COONH4 in H2O, B) 5 mmol/L CH3COONH4 in CH3OH
Gradient:
Time (min) | B conc. (%) |
---|---|
0-1 | 15-40 |
1-3.5 | 40 |
3.5-6 | 40-50 |
6-8 | 50-55 |
8-17.5 | 55-95 |
17.5-30 | 95 |
30 -40 | 95-15 |
Flow rate: 0.2 mL/min
[MS]
Ionization: ESI
Mode: MRM
VPL1-VPL2
Veterinary Drug Mixture Standard Solution PL-1-3 (each 20μg/ml Methanol Solution)
LC/MS/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | ||
---|---|---|---|---|---|---|---|---|---|
Precursor | Product | Precursor | Product | ||||||
1 | Lincomycin** | 407.2 | 126.2 | + | 12 | Dexamethasone | 393.2 | 337.0 | + |
2 | Sulfacetamide | 215.1 | 155.9 | + | 13 | Emamectin B1a | 887.6 | 158.1 | + |
3 | Danofloxacin** | 358.2 | 82.0 | + | 14 | Famphur | 326.1 | 92.8 | + |
4 | Clenbuterol ** | 277.1 | 203.0 | + | 15 | Fenobucarb (BPMC) | 208.2 | 95.0 | + |
5 | Xylazine ** | 221.3 | 90.0 | + | 16 | Temephos (Abate) | 467.0 | 124.9 | + |
6 | Pyrimethamine | 249.1 | 176.9 | + | 17 | Allethrin | 303.2 | 135.1 | + |
7 | Trichlorfon (DEP) | 257.1 | 108.8 | + | 18 | Monensin | 688.4 | 125.1 | + |
8 | Tilmicosin | 869.5 | 174.0 | + | 19 | Florfenicol | 358.1 | 185.1 | − |
9 | 494.3 | 192.1 | + | 20 | 2-Acetylamino-5-nitro thiazole | 186.2 | 139.1 | − | |
10 | Prednisolone | 361.2 | 147.0 | + | 21 | Clorsulon | 380.0 | 344.0 | − |
11 | Hydrocortisone | 363.3 | 121.0 | + |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
- **The preparation concentration is converted to 20 µg/mL as a free base.
Analysis conditions
[ Instrument ]
Shimadzu LCMS-8040
[HPLC]
Column: Wakopak® Wakosil-Ⅱ 3C18HG 3.0 × 150 mm
Column temperature: 40 ℃
Eluent: A) 0.1% HCOOH in H2O, B) 0.1% HCOOH in CH3CN
Gradient:
Time (min) | B conc. (%) |
---|---|
0-35 | 1-100 |
35-40 | 100 |
Flow rate: 0.2 mL/min
[MS]
Ionization: ESI
Mode: MRM
Veterinary Drug Mixture Standard Solution PL-2-1 (each 20μg/ml Methanol Solution)
LC/MS/MS Chromatogram*
Peak No. | Constituent | Monitoring Ions (m/z) | Mode | Peak No. | Constituent | Monitoring Ions (m/z) | Mode | ||
---|---|---|---|---|---|---|---|---|---|
Precursor | Product | Precursor | Product | ||||||
1 | 5-Propylsulfonyl-1H-benzimidazole-2-amine | 240.1 | 133.1 | + | 13 | Sulfachlorpyridazine** | 286.2 | 156.9 | + |
2 | Levamisole** | 207.1 | 180.0 | + | 14 | Sulfadoxine | 311.1 | 155.9 | + |
3 | Thiabendazole | 202.2 | 174.9 | + | 15 | Sulfamethoxazole | 254.1 | 156.0 | + |
4 | Trimethoprim | 291.2 | 230.0 | + | 16 | Ethopabate | 238.3 | 136.0 | + |
5 | Sulfadiazine | 251.1 | 155.9 | + | 17 | Sulfadimethoxine | 311.1 | 156.0 | + |
6 | Ormetoprim | 275.2 | 123.1 | + | 18 | Sulfaquinoxaline** | 301.1 | 156.0 | + |
7 | Sulfathiazole | 256.1 | 155.9 | + | 19 | β-Trenbolone | 271.2 | 199.0 | + |
8 | Sulfapyridine | 250.1 | 156.0 | + | 20 | α-Trenbolone | 271.2 | 199.0 | + |
9 | Sulfamerazine | 265.1 | 92.1 | + | 21 | Melengestrol Acetate | 397.3 | 279.0 | + |
10 | Sulfadimidine | 279.1 | 92.1 | + | 22 | Thiamphenicol | 356.1 | 185.1 | − |
11 | Sulfamethoxypyridazine | 281.1 | 156.1 | + | 23 | Zeranol | 321.3 | 277.4 | − |
12 | Sulfamonomethoxine | 281.1 | 156.0 | + | 24 | Sulfanitran | 334.0 | 136.1 | − |
- *Analysis conditions, charts, and detected ions are reference data. It is not the data to guarantee the pesticide mixed standard solution.
- **The preparation concentration is converted to 20 µg/mL as a free base.
Analysis conditions
[ Instrument ]
Shimadzu LCMS-8040
[HPLC]
Column: Wakopak® Wakosil-Ⅱ 3C18HG 3.0 × 150mm
Column temperature: 40 ℃
Eluent: A) 0.1% HCOOH in H2O, B) 0.1% HCOOH in CH3CN
Gradient:
Time (min) | B conc. (%) |
---|---|
0-35 | 1-100 |
35-40 | 100 |
Flow rate: 0.2 mL/min
[MS]
Ionization: ESI
Mode: MRM
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Mixture Standard of Pesticides
Veterinary Drug Mixture Standard Solutions
For research use or further manufacturing use only. Not for use in diagnostic procedures.
Product content may differ from the actual image due to minor specification changes etc.
If the revision of product standards and packaging standards has been made, there is a case where the actual product specifications and images are different.